The coupling involving the ion partitioning and polyelectrolyte ionization degree is simply partially by the classical Donnan principle.

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On top of that, the gel functions being a processing support once the cable is becoming produced, retaining the fibers central even though the tube content is extruded all around it.

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This modulus can then be equated to osmotic stress (through differentiation read more of your free Electrical power) to give the identical equation as we found earlier mentioned.

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As a starting point we can neglect the electrostatic interactions among ions. Then at equilibrium, a few of the weak acid websites in the gel would dissociate to sort A − displaystyle textual content A ^ -

We now think about the two contributions independently. The polymer elastic deformation expression is independent of the solvent section and has exactly the same expression as being a rubber, as derived inside the Kuhn's idea of rubber elasticity:

where on the right-hand facet, the primary term could be the Flory–Huggins check here Strength density of the final swollen gel, the next is linked to the Preliminary gel along with the 3rd is of the pure solvent ahead of read more mixing.

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